I just finished watching Al's interview and I will say it's worth it. It's nice to see him not being "On" and getting to talk about things as an artist.
Here's the important stuff
-He comes on about 40 minutes into the first hour (Though he also "intros" the show and there's a quick shot of him walking into the studio, for the completists and Al Gals out there). Coincidentally, he comes on just in time for video #......14
-They didn't play all of White & Nerdy

Though they did play a good amount of it to fit it into the show (And, for our purposes, enough to get it into the minds of the people who watch the show)
-No mentions of Coolio or Eminem!

They talk about how Chamillionaire likes the song...but Al does a self inflicted vague mention of them. (This is great, though there's some derision in Al's voice about how it was on Chamillionaire's MySpace before his....but I'm sure that's a non issue now that the songs out and Al got a good amount of promotion from it)
-Video #14 was the OK Go on treadmills video. Not surprisingly, Al loves it (And the band)
-He gets further into a topic in the CD101 interview, that it's harder to find a song to parody. He says how Ridin' was an obvious choice
-He reveals some new production details about W&N
-Matt asks him what Green Day song is being parodied. Al says it's Canadian Idiot....he doesn't want to give away what it parodies

He also briefly touches on Trapped in the Drive Thru (And reiterates his thoughts on the original)
-They talk about the dualdisc and the animated videos. Clips of DDTS, Close But no Cigar and Weasel Stomping Day are shown, although every director is mentioned.
-The interview (With a couple videos mixed in) takes up the entire segmant.
It was a great interview. Pinfield can be annoying (I like him though), but he's no dummy. He's one of the biggest music geeks on the planet and he's not gonna ask the stupid questions we've all become used to (And I've always suspected he's a closet Al fan too). The interview came out exactly like I thought it would.
EDIT: Revealed at the end of the show,W&N is now a listed video for countdown eligibility! So go! Vote!